Volume 7, Issue 1
Hydrophobicity and Phase Changes of Pd/SiO2 Organic-inorganic Hybrid Materials Calcined in Air Atmosphere

Jing Yang, Baosong Li, Hao Xu, Yue Li & Xiang Huo

Journal of Fiber Bioengineering & Informatics, 7 (2014), pp. 117-127.

Published online: 2014-07

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  • Abstract

Pd/SiO_2 organic-inorganic hybrid material was prepared by sol-gel method, in which PdCl_2 was added into methyl-modified silica sol. The Pd/SiO_2 sol particle size distribution, the hydrophobicity and phase changes of Pd/SiO_2 hybrid materials calcined at 200, 350, 500, 600 and 750 °C in air atmosphere were discussed. The Pd/SiO_2 sol system exhibits moderate dispersion and the mean particle size of Pd/SiO_2 sol is 2.70 nm. When the calcination temperature is raised to 350 °C, metallic palladium of high crystallinity is formed in the Pd/SiO_2 sample. PdO occurs in minor quantities in the Pd/SiO_2 sample calcined at 500 °C, which increases in amount in the samples calcined at 600 and 750 °C. With the increase of calcination temperature, the Si-CH_3 and Si-OH bands in Pd/SiO_2 materials are found to decrease in absorption intensity and the hydrophobicity on Pd/SiO_2 film surfaces increases. The water contact angle on the Pd/SiO_2 film surface achieves the maximum value as the calcination temperature is up to 350 °C and the particle sizes of the formed metallic Pd are about 15 ∼ 20 nm. The optimal calcination temperature for hydrophobic Pd/SiO_2 membrane materials is about 350 °C.

  • Keywords

Sol-gel Method Palladium Doping Hydrophobicity Phase Change

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@Article{JFBI-7-117, author = {}, title = {Hydrophobicity and Phase Changes of Pd/SiO2 Organic-inorganic Hybrid Materials Calcined in Air Atmosphere}, journal = {Journal of Fiber Bioengineering and Informatics}, year = {2014}, volume = {7}, number = {1}, pages = {117--127}, abstract = {Pd/SiO_2 organic-inorganic hybrid material was prepared by sol-gel method, in which PdCl_2 was added into methyl-modified silica sol. The Pd/SiO_2 sol particle size distribution, the hydrophobicity and phase changes of Pd/SiO_2 hybrid materials calcined at 200, 350, 500, 600 and 750 °C in air atmosphere were discussed. The Pd/SiO_2 sol system exhibits moderate dispersion and the mean particle size of Pd/SiO_2 sol is 2.70 nm. When the calcination temperature is raised to 350 °C, metallic palladium of high crystallinity is formed in the Pd/SiO_2 sample. PdO occurs in minor quantities in the Pd/SiO_2 sample calcined at 500 °C, which increases in amount in the samples calcined at 600 and 750 °C. With the increase of calcination temperature, the Si-CH_3 and Si-OH bands in Pd/SiO_2 materials are found to decrease in absorption intensity and the hydrophobicity on Pd/SiO_2 film surfaces increases. The water contact angle on the Pd/SiO_2 film surface achieves the maximum value as the calcination temperature is up to 350 °C and the particle sizes of the formed metallic Pd are about 15 ∼ 20 nm. The optimal calcination temperature for hydrophobic Pd/SiO_2 membrane materials is about 350 °C.}, issn = {2617-8699}, doi = {https://doi.org/10.3993/jfbi03201410}, url = {http://global-sci.org/intro/article_detail/jfbi/4771.html} }
TY - JOUR T1 - Hydrophobicity and Phase Changes of Pd/SiO2 Organic-inorganic Hybrid Materials Calcined in Air Atmosphere JO - Journal of Fiber Bioengineering and Informatics VL - 1 SP - 117 EP - 127 PY - 2014 DA - 2014/07 SN - 7 DO - http://doi.org/10.3993/jfbi03201410 UR - https://global-sci.org/intro/article_detail/jfbi/4771.html KW - Sol-gel Method KW - Palladium Doping KW - Hydrophobicity KW - Phase Change AB - Pd/SiO_2 organic-inorganic hybrid material was prepared by sol-gel method, in which PdCl_2 was added into methyl-modified silica sol. The Pd/SiO_2 sol particle size distribution, the hydrophobicity and phase changes of Pd/SiO_2 hybrid materials calcined at 200, 350, 500, 600 and 750 °C in air atmosphere were discussed. The Pd/SiO_2 sol system exhibits moderate dispersion and the mean particle size of Pd/SiO_2 sol is 2.70 nm. When the calcination temperature is raised to 350 °C, metallic palladium of high crystallinity is formed in the Pd/SiO_2 sample. PdO occurs in minor quantities in the Pd/SiO_2 sample calcined at 500 °C, which increases in amount in the samples calcined at 600 and 750 °C. With the increase of calcination temperature, the Si-CH_3 and Si-OH bands in Pd/SiO_2 materials are found to decrease in absorption intensity and the hydrophobicity on Pd/SiO_2 film surfaces increases. The water contact angle on the Pd/SiO_2 film surface achieves the maximum value as the calcination temperature is up to 350 °C and the particle sizes of the formed metallic Pd are about 15 ∼ 20 nm. The optimal calcination temperature for hydrophobic Pd/SiO_2 membrane materials is about 350 °C.
Jing Yang, Baosong Li, Hao Xu, Yue Li & Xiang Huo. (2019). Hydrophobicity and Phase Changes of Pd/SiO2 Organic-inorganic Hybrid Materials Calcined in Air Atmosphere. Journal of Fiber Bioengineering and Informatics. 7 (1). 117-127. doi:10.3993/jfbi03201410
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