Volume 5, Issue 2
Study of Polyelectrolyte Adsorbent Theory on a Repulsive Charged Surface

Meng-Chun Lu, Yong-Lin Zheng, Xiao-Xi Wang, Zheng-Hua Luo, Gang-Feng Yan & Xiao-Bin Tian

J. At. Mol. Sci., 5 (2014), pp. 123-131.

Published online: 2014-05

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  • Abstract

Applying scaling theory of polyelectrolyte adsorption, and according to ratio of the dielectric constant between the medium and the substrate, and taking into account strong interaction between polyelectrolytes of multivalency adsorption, we proposed a scaling theory of the approximation method on a repulsive charged surface. It is divided into two kind phase diagrams that one is qualitatively different. This shows when the surface charge density is low (or the bulk counterion density is high), the surface and the bulk counterion density are almost the same. Once the surface charge density is high enough, counterions condense on the surface. In this regime, polyelectrolytes of lower valency form a correlated many-chain state. As their valency is high enough, the state turns out to be single-chain because of stronger repulsion between neighboring chains.

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@Article{JAMS-5-123, author = {Lu , Meng-ChunZheng , Yong-LinWang , Xiao-XiLuo , Zheng-HuaYan , Gang-Feng and Tian , Xiao-Bin}, title = {Study of Polyelectrolyte Adsorbent Theory on a Repulsive Charged Surface}, journal = {Journal of Atomic and Molecular Sciences}, year = {2014}, volume = {5}, number = {2}, pages = {123--131}, abstract = {

Applying scaling theory of polyelectrolyte adsorption, and according to ratio of the dielectric constant between the medium and the substrate, and taking into account strong interaction between polyelectrolytes of multivalency adsorption, we proposed a scaling theory of the approximation method on a repulsive charged surface. It is divided into two kind phase diagrams that one is qualitatively different. This shows when the surface charge density is low (or the bulk counterion density is high), the surface and the bulk counterion density are almost the same. Once the surface charge density is high enough, counterions condense on the surface. In this regime, polyelectrolytes of lower valency form a correlated many-chain state. As their valency is high enough, the state turns out to be single-chain because of stronger repulsion between neighboring chains.

}, issn = {2079-7346}, doi = {https://doi.org/10.4208/jams.080513.111013a}, url = {http://global-sci.org/intro/article_detail/jams/8315.html} }
TY - JOUR T1 - Study of Polyelectrolyte Adsorbent Theory on a Repulsive Charged Surface AU - Lu , Meng-Chun AU - Zheng , Yong-Lin AU - Wang , Xiao-Xi AU - Luo , Zheng-Hua AU - Yan , Gang-Feng AU - Tian , Xiao-Bin JO - Journal of Atomic and Molecular Sciences VL - 2 SP - 123 EP - 131 PY - 2014 DA - 2014/05 SN - 5 DO - http://doi.org/10.4208/jams.080513.111013a UR - https://global-sci.org/intro/article_detail/jams/8315.html KW - dielectric constant, polyelectrolyte, charged of surface, adsorbent theory. AB -

Applying scaling theory of polyelectrolyte adsorption, and according to ratio of the dielectric constant between the medium and the substrate, and taking into account strong interaction between polyelectrolytes of multivalency adsorption, we proposed a scaling theory of the approximation method on a repulsive charged surface. It is divided into two kind phase diagrams that one is qualitatively different. This shows when the surface charge density is low (or the bulk counterion density is high), the surface and the bulk counterion density are almost the same. Once the surface charge density is high enough, counterions condense on the surface. In this regime, polyelectrolytes of lower valency form a correlated many-chain state. As their valency is high enough, the state turns out to be single-chain because of stronger repulsion between neighboring chains.

Meng-Chun Lu, Yong-Lin Zheng, Xiao-Xi Wang, Zheng-Hua Luo, Gang-Feng Yan & Xiao-Bin Tian. (1970). Study of Polyelectrolyte Adsorbent Theory on a Repulsive Charged Surface. Journal of Atomic and Molecular Sciences. 5 (2). 123-131. doi:10.4208/jams.080513.111013a
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