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The non-relativistic energies and wavefunctions of $1s^2np$ and $1s^2nd$ states for $Zn^{27+}$ ion are obtained by using the full-core plus correlation method. The expectation values of the spin-orbit and spin-other-orbit interaction operators in these states are calculated. By introducing the effective nuclear charge, the higher-order relativistic contribution and QED correction to the fine structure splittings are estimated.
}, issn = {2079-7346}, doi = {https://doi.org/10.4208/jams.032211.041611a}, url = {http://global-sci.org/intro/article_detail/jams/8284.html} }The non-relativistic energies and wavefunctions of $1s^2np$ and $1s^2nd$ states for $Zn^{27+}$ ion are obtained by using the full-core plus correlation method. The expectation values of the spin-orbit and spin-other-orbit interaction operators in these states are calculated. By introducing the effective nuclear charge, the higher-order relativistic contribution and QED correction to the fine structure splittings are estimated.