@Article{JAMS-8-117, author = {Zhuang , XinSong , JunmeiSun , LuyanWang , Tiantian and Liu , Xinguo}, title = {Influences of the Low Collision Energies and Isotopic Variants on the Stereodynamics for Reactions Li+DF/TF→LiF+D/T}, journal = {Journal of Atomic and Molecular Sciences}, year = {2017}, volume = {8}, number = {3}, pages = {117--121}, abstract = {
Stereodynamics for Li+DF/TF→LiF+D/T reactions are studied using the quasi-classical trajectory method based on a new potential energy surface constructed by Aguado and Paniaga [J. Chem. Phys. 119 (2003) 10088]. The product angular distributions of $P(θ_r)$ and $P(\phi_r),$ which reflect the vector correlation, are calculated and discussed. The average rotational alignment factor $〈P_2(cosθ_r)〉$ as function of the collision energy is also presented. Furthermore, four polarization-dependent differential cross sections (PDDCSs), namely, ${\rm PDDCS}_{00},$ ${\rm PDDCS}_{20},$ ${\rm PDDCS}_{21-}$ and ${\rm PDDCS}_{22+}$ are calculated as well. By comparing the stereodynamics results of the title reactions, we find that the isotopic effects are relatively obvious.
}, issn = {2079-7346}, doi = {https://doi.org/10.4208/jams.101317.121217a}, url = {http://global-sci.org/intro/article_detail/jams/12552.html} }