We present a decoupled, linearly implicit numerical scheme with energy stability and mass conservation for solving the coupled Cahn-Hilliard system. The time-discretization is done by leap-frog method with the scalar auxiliary variable (SAV) approach. It only needs to solve three linear equations at each time step, where each unknown variable can be solved independently. It is shown that the semi-discrete scheme has second-order accuracy in the temporal direction. Such convergence results are proved by a rigorous analysis of the boundedness of the numerical solution and the error estimates at different time-level. Numerical examples are presented to further confirm the validity of the methods.